INVESTIGATION OF AN ELECTRONIC ELECTRODE IN HEXAMETHYLPHOSPHORIC TRIAMIDE BY IMPEDANCE MEASUREMENTS

被引：0
|
作者：
OVSYANNIKOVA, EV [1 ]
KRISHTALIK, LI [1 ]
NOVITSKII, SP [1 ]
BURENKOV, II [1 ]
ALPATOVA, NM [1 ]
机构：
[1] ACAD SCI USSR,INST RAW MINERAL PROC,NOVOSIBIRSK,USSR
来源：
SOVIET ELECTROCHEMISTRY | 1982年 / 18卷 / 07期
关键词：
ELECTRONIC ELECTRODE - LITHIUM CHLORIDE;
D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The behavior of an equilibrium electronic electrode in a solution of lithium chloride in hexamethylphosphoric triamide containing solvated electrons has been investigated by impedance methods. It is shown that in the system investigated, in which the concentration of the potential-determining particles, i. e. , the solvated electrons, and the state of the surface of the metallic electrode can vary with time, reliable information on the components of the impedance can be obtained only with the aid of a high-speed device for measuring the impedance. The decisive influence of the state of the electrode surface, assigned by preliminary polarization of the electrode, has been established.
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页码：769 / 775
页数：7
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