Dimethyl 2,2 '-[Carbonylbis(azanediyl)](2S,2 ' S)-bis[3-(4-hydroxyphenyl)propanoate]

被引：0
|
作者：
Mancuso, Raffaella [1 ]
Gioia, Katia F. [1 ]
Piccionello, Antonio Palumbo [2 ]
Della Ca', Nicola [3 ]
Carfagna, Carla [4 ]
Gabriele, Bartolo [1 ]
机构：
[1] Univ Calabria, Dept Chem & Chem Technol, Lab Ind & Synthet Organ Chem, Via Pietro Bucci 12-C, I-87036 Arcavacata Di Rende, CS, Italy
[2] Univ Palermo, Dipartimento Sci & Tecnol Biol Chim Farmaceut, STEBICEF, Viale Sci Ed 17, I-90128 Palermo, Italy
[3] Univ Parma, Dept Chem Life Sci & Environm Sustainabil SCVSA, Parco Area Sci 17-A, I-43124 Parma, Italy
[4] Univ Bologna, Dept Ind Chem T Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy
来源：
MOLBANK | 2018年 / 01期
关键词：
carbonylation; palladium; L-tyrosine methyl ester; ureas;
D O I：
10.3390/M983
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The thus-far unknown ureic derivative dimethyl 2,2'-[carbonylbis(azanediyl)](2S,2'S)-bis[3-(4-hydroxyphenyl) propanoate] has been efficiently synthesized by enantiospecific oxidative carbonylation of readily available L-tyrosine methyl ester, using a very simple catalytic system (PdI2 in conjunction with KI) under relatively mild conditions (100 degrees C for 5 h in DME as the solvent and under 20 atm of a 4:1 mixture CO-air).
引用
收藏
页数：3
相关论文
共 50 条
  • [31] SYNTHESIS AND CONVERSIONS OF 2,2-BIS(4-HYDROXYPHENYL)PROPANE NITRO-DERIVATIVES
    STROGANOV, VF
    SMIRNOV, SP
    MOSHCHIN.NK
    ZHURNAL ORGANICHESKOI KHIMII, 1973, 9 (08): : 1713 - 1717
  • [32] THE SYNTHESIS AND REACTIONS OF POLYSULFITES DERIVED FROM 2,2-BIS(4-HYDROXYPHENYL)PROPANE
    HALLGREN, JE
    MATTHEWS, RO
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (05) : 1615 - 1617
  • [33] (2S)-Methyl 2-(p-toluenesulfonamido)propanoate
    Syed, Tayyaba
    Hameed, Shahid
    Jones, Peter G.
    Schmidt-Meier, Andrea
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O1300 - U2043
  • [34] (2,2′-Bipyridyl)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]cadmium(II)
    Song, Juyoung C.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1667 - U1458
  • [35] 2,2′-bipyridyl)bis(O,O′-diisobutyl dithiophosphato-κ2S,S′)nickel(II)
    Berdugo, Erick
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M2218 - M2220
  • [36] 7-Methoxy-2,2-dimethyl-3-phenyl-4-(4-hydroxyphenyl)-2H-1-benzopyran
    Central Drug Research Inst, Lucknow, India
    Acta Crystallographica, Section C: Crystal Structure Communications, 1998, 54 (pt 1): : 134 - 136
  • [37] μ-ferrio-bis{carbonyl[μ-2,2′,2"-nitrilotriethanethiolato(3-)-N,S,S′,S":S,S′]iron(II)} benzene solvate
    Davies, SC
    Smith, MC
    Hughes, DL
    Evans, DJ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : M658 - M660
  • [38] 7-methoxy-2,2-dimethyl-3-phenyl-4-(4-hydroxyphenyl)2H-1-benzopyran
    Ray, S
    Sarkhel, S
    Maulik, PR
    Lobkovsky, E
    Clardy, J
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1998, 54 : 134 - 136
  • [39] First Enantioselective Synthesis of (2R,3R)-and(2S,3S)-2-(4-hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxan-6-carbaldehyde
    Wen Xin GU
    Chinese Chemical Letters, 2001, (03) : 189 - 192
  • [40] First enantioselective synthesis of (2R,3R)- and (2S,3S)-2-(4-hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxan-6-carbaldehyde
    Gu, WX
    Jing, XB
    Chen, XC
    Pan, XF
    CHINESE CHEMICAL LETTERS, 2001, 12 (03) : 189 - 192
12345