Dimethyl 2,2 '-[Carbonylbis(azanediyl)](2S,2 ' S)-bis[3-(4-hydroxyphenyl)propanoate]

被引：0

作者：

Mancuso, Raffaella ^{[1
]}

Gioia, Katia F. ^{[1
]}

Piccionello, Antonio Palumbo ^{[2
]}

Della Ca', Nicola ^{[3
]}

Carfagna, Carla ^{[4
]}

Gabriele, Bartolo ^{[1
]}

机构：

[1] Univ Calabria, Dept Chem & Chem Technol, Lab Ind & Synthet Organ Chem, Via Pietro Bucci 12-C, I-87036 Arcavacata Di Rende, CS, Italy

[2] Univ Palermo, Dipartimento Sci & Tecnol Biol Chim Farmaceut, STEBICEF, Viale Sci Ed 17, I-90128 Palermo, Italy

[3] Univ Parma, Dept Chem Life Sci & Environm Sustainabil SCVSA, Parco Area Sci 17-A, I-43124 Parma, Italy

[4] Univ Bologna, Dept Ind Chem T Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy

来源：

MOLBANK | 2018年 / 01期

关键词：

carbonylation; palladium; L-tyrosine methyl ester; ureas;

D O I：

10.3390/M983

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The thus-far unknown ureic derivative dimethyl 2,2'-[carbonylbis(azanediyl)](2S,2'S)-bis[3-(4-hydroxyphenyl) propanoate] has been efficiently synthesized by enantiospecific oxidative carbonylation of readily available L-tyrosine methyl ester, using a very simple catalytic system (PdI2 in conjunction with KI) under relatively mild conditions (100 degrees C for 5 h in DME as the solvent and under 20 atm of a 4:1 mixture CO-air).

引用

页数：3

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