THE SYNTHESIS, STRUCTURE AND REDOX PROPERTIES OF THE [FE3(CO)9S]2- DIANION

被引：0

作者：

ZHIGUI, Z ^{[1
]}

LIXIN, W ^{[1
]}

HENGBIN, Z ^{[1
]}

LING, Y ^{[1
]}

YUGUO, F ^{[1
]}

机构：

[1] JILIN UNIV,INST THEORET CHEM,CHANGCHUN,PEOPLES R CHINA

来源：

EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1991年 / 28卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of [Bu4N]2 [Fe3 (CO)9S] were prepared with (NH4)2MoS4, Fe(CO)5 and Bu4NBr as starting materials, and their structure was determined by X-ray diffraction. They belong to the triclinic space group P1BAR with a = 10.969(2) angstrom, b = 12.472(3) angstrom, c = 20.363(5) angstrom, alpha = 100.89-degrees, beta = 97.12-degrees, gamma = 108.07-degrees, V = 2550.6(4) angstrom 3 and Z = 2. The block least-square refinement of all structure parameters gave a final discrepancy factor R = 0.089. Redox characteristics of the cluster dianion, [Fe3(CO)9S]2-, have been studied by cyclic voltammetry.

引用

页码：1269 / 1276

页数：8

共 50 条

[21] SIMPLE SYNTHESIS OF FE3(CO)9(MU3PR)2 COMPLEXES
LAMPIN, JP
MATHEY, F
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1976, 282 (20): : 979 - 980
[22] SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF FE3(CO)9(MU-3-PCL)2
JORDAN, MR
SCHAUER, CK
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 340 - INOR
[23] Synthesis, structure, and characterization of the [Fe5S4(CO)12]2- ions and studies on the oxidative conversion of the dianion to [Fe6S6(CO)12]2-
Barber, D.E.
Sabat, M.
Sinn, E.
Averill, B.A.
Organometallics, 1995, 14 (07)
[24] THE PREPARATION AND CRYSTAL-STRUCTURE OF FE3(CO)9(MU-3-PPH)2
COOK, SL
EVANS, J
GRAY, LR
WEBSTER, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 236 (03) : 367 - 374
[25] Metal complexes of the bridging bidentate metallophosphine ligand, [Fe3(CO)9(μ3-P)2]2-
1600, (113):
[26] CLUSTER MIMETICS .2. THE PREPARATION AND CHARACTERIZATION OF (MU-H)(MU-CO)FE3(CO)9BH2, (MU-CO)FE3(CO)9BH2-, AND FE3(CO)9BH4-
VITES, JC
HOUSECROFT, CE
JACOBSEN, GB
FEHLNER, TP
ORGANOMETALLICS, 1984, 3 (10) : 1591 - 1593
[27] PH-AS AS COMPLEX LIGAND - STRUCTURE OF FE3(CO)9(PH-AS)2
HUTTNER, G
MOHR, G
FRANK, A
SCHUBERT, U
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 118 (03) : C73 - C77
[28] Unexpected fragmentation of the Fe3(CO)9(μ3-Se) (μ3-AsCH3) cluster core in the reaction with CpCo(CO)2:: synthesis and structure of Fe3(CO)6(μ3-Se) (μ-AsCH3{CpFe(CO)2})2(μ-CO)
Konchenko, SN
Virovets, AV
Pushkarevsky, NA
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (11) : 552 - 554
[29] SYNTHESIS AND REACTIVITY OF [FE-3(CO)(9)TE](2-)
ROOF, LC
SMITH, DM
DRAKE, GW
PENNINGTON, WT
KOLIS, JW
INORGANIC CHEMISTRY, 1995, 34 (01) : 337 - 345
[30] MOSSBAUER-EFFECT STUDY OF FE3(CO)12 AND THE REDUCED CARBIDE CLUSTERS (PPN)[FE3(CO)10CH],(PPN)2[FE3(CO)9CCO], AND (PPN)[FE2CO(CO)9CCO]
BENSON, CG
LONG, GJ
KOLIS, JW
SHRIVER, DF
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (18) : 5297 - 5298

← 1 2 3 4 5 →