THE SYNTHESIS, STRUCTURE AND REDOX PROPERTIES OF THE [FE3(CO)9S]2- DIANION

被引：0

作者：

ZHIGUI, Z ^{[1
]}

LIXIN, W ^{[1
]}

HENGBIN, Z ^{[1
]}

LING, Y ^{[1
]}

YUGUO, F ^{[1
]}

机构：

[1] JILIN UNIV,INST THEORET CHEM,CHANGCHUN,PEOPLES R CHINA

来源：

EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1991年 / 28卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of [Bu4N]2 [Fe3 (CO)9S] were prepared with (NH4)2MoS4, Fe(CO)5 and Bu4NBr as starting materials, and their structure was determined by X-ray diffraction. They belong to the triclinic space group P1BAR with a = 10.969(2) angstrom, b = 12.472(3) angstrom, c = 20.363(5) angstrom, alpha = 100.89-degrees, beta = 97.12-degrees, gamma = 108.07-degrees, V = 2550.6(4) angstrom 3 and Z = 2. The block least-square refinement of all structure parameters gave a final discrepancy factor R = 0.089. Redox characteristics of the cluster dianion, [Fe3(CO)9S]2-, have been studied by cyclic voltammetry.

引用

页码：1269 / 1276

页数：8

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