IMPEDANCE SPECTROSCOPY ANALYSIS OF WO3 THIN-FILM ELECTRODES DURING ELECTROCHROMIC COLORING-BLEACHING CYCLING

被引:3
|
作者
BOHNKE, C
REZRAZI, M
机构
[1] Laboratoire d'Electrochimie des Solides (Unité associée au CNRS 436), Unité de Formation et de Recherche des Sciences et des Techniques
关键词
D O I
10.1016/0921-5107(91)90107-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper deals with the variations in the electrical components (resistances, capacitances and constant phase element) of an electrochromic electrode during colouring-bleaching cycling. The complex impedance method is used to determine these parameters. Two types of electrochromic material are investigated: tungsten trioxide thin films obtained by anodic oxidation of tungsten sheet or by thermal vacuum evaporation of WO3 onto an SnO2:F electrode. An electrical model can be associated with the electrochromic electrode. The behaviours of these electrodes during cycling are compared and explained in terms of interface modification.
引用
收藏
页码:313 / 320
页数:8
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