INTRAMOLECULAR AND INTERMOLECULAR PALLADIUM-CATALYZED ASYMMETRIC ALLYLATIONS OF CHIRAL ENAMINES

被引：10
|
作者：
HIROI, K
ABE, J
机构：
[1] Department of Synthetic Organic Chemistry, Tohoku College of Pharmacy, Aoba-ku, Sendai, Miyagi, 981
来源：
HETEROCYCLES | 1990年 / 30卷 / 01期
关键词：
D O I：
10.3987/COM-89-S34
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Stereochemistry of intramolecular palladium-catalyzed asymmetric allylations of chiral enamines involving allylating species in the molecules is discussed, compared with that of intermolecular reactions. The mechanistic pathway for this asymmetric induction is proposed on the basis of the stereochemical results. © 1990.
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页码：283 / 286
页数：4
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