PALLADIUM-CATALYZED ASYMMETRIC ALLYLATIONS OF CHIRAL ENAMINES BEARING PHOSPHINE FUNCTIONALITY - EFFECTS OF ANIONIC COUNTERPARTS OF ALLYLATING REAGENTS ON ASYMMETRIC INDUCTION

被引：27
|
作者：
HIROI, K
ABE, J
机构：
[1] Department of Synthetic Organic Chemistry, Tohoku College of Pharmacy, Aoba-ku, Sendai, Miyagi, 981
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 25期
关键词：
D O I：
10.1016/S0040-4039(00)94460-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed asymmetric allylations of chiral enamines bearing a phosphine group were attempted using various allylating reagents to produce optically active α-allyl carbonyl compounds. The great effects of the anionic counterparts of the allylating reagents on asymmetric induction were observed. © 1990.
引用
收藏
页码：3623 / 3626
页数：4
相关论文
共 50 条
12345