KINETIC RESOLUTION OF RACEMIC CARBOXYLIC-ACIDS WITH HOMOCHIRAL ALCOHOLS AND DICYCLOHEXYLCARBODIIMIDE

被引：22

作者：

CHINCHILLA, R

NAJERA, C

YUS, M

HEUMANN, A

机构：

[1] UNIV ALICANTE,FAC CIENCIAS,DEPT QUIM ORGAN,E-03690 ALACANT,SPAIN

[2] UNIV AIX MARSEILLE,CTR ST JEROME,ENSSPICAM,URA 1410,F-13013 MARSEILLE,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(00)80527-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Racemic carboxylic acids have been kinetically resolved by means of homochiral alcohols using the DCC-esterification methodology. The best results were obtained with commercially available homochiral 1-(4-pyridyl)ethanol: < 60% e.e. for enantiomerically enriched acids and < 76% d.e. for diastereomerically enriched esters.

引用

页码：101 / 104

页数：4

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