OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .5. A NOVEL TYPE OF OPTICALLY-ACTIVE DIKETONATE LIGAND AND ITS RHODIUM COMPLEX

被引：4

作者：

ENGLERT, U ^{[1
]}

KASER, M ^{[1
]}

SALZER, A ^{[1
]}

机构：

[1] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52056 AACHEN,GERMANY

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 25期

关键词：

D O I：

10.1021/ic00129a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An optically active tricarbonyl(eta(4)-dienone)iron complex is deprotonated to its enolate, which can be converted either with TMSCl into a silylenol ether or with pivaloyl chloride into a beta-dicarbonyl compound. The latter is deportonated to give a diketonate, which serves as a chiral chelating ligand toward rhodium.

引用

页码：6231 / &

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