OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .5. A NOVEL TYPE OF OPTICALLY-ACTIVE DIKETONATE LIGAND AND ITS RHODIUM COMPLEX

被引：4

作者：

ENGLERT, U ^{[1
]}

KASER, M ^{[1
]}

SALZER, A ^{[1
]}

机构：

[1] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52056 AACHEN,GERMANY

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 25期

关键词：

D O I：

10.1021/ic00129a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An optically active tricarbonyl(eta(4)-dienone)iron complex is deprotonated to its enolate, which can be converted either with TMSCl into a silylenol ether or with pivaloyl chloride into a beta-dicarbonyl compound. The latter is deportonated to give a diketonate, which serves as a chiral chelating ligand toward rhodium.

引用

页码：6231 / &

共 50 条

[31] HYDROGENATION OF PROCHIRAL OLEFINS WITH RHODIUM COMPLEXES OF OPTICALLY-ACTIVE AMIDINES
BRUNNER, H
AGRIFOGLIO, G
MONATSHEFTE FUR CHEMIE, 1980, 111 (01): : 275 - 287
[32] OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .92. GEOMETRICAL AND OPTICAL ISOMERS IN THE DIBENZOCHROMIUM SERIES
BRUNNER, H
ERNST, J
WISCHERT, T
THEWALT, U
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 328 (03) : 331 - 339
[33] COMPLEXES OF AN OPTICALLY-ACTIVE PHOSPHITE ESTER
WROBLEWSKI, A
VERKADE, JG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 415 - 415
[34] SYNTHESIS OF DIASTEREOISOMERIC TRANSITION-METAL COMPLEXES WITH 5 DIFFERENT AND INDEPENDENT LIGANDS - RESOLUTION THROUGH AN OPTICALLY-ACTIVE GERMANIUM
CERVEAU, G
COLOMER, E
CORRIU, RJP
VIOUX, A
ORGANOMETALLICS, 1982, 1 (06) : 866 - 867
[35] OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .36. ATROPOUS ISOMERS OF AMINOCARBENE PENTACARBONYLCHROMIUM(O) COMPLEXES
BRUNNER, H
DOPPELBERGER, J
FISCHER, EO
LAPPUS, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 112 (01) : 65 - 78
[36] DIASTEREOSELECTIVE C-H BOND ACTIVATION BY OPTICALLY-ACTIVE TRISPYRAZOLYLBORATE TRANSITION-METAL COMPLEXES
KEYES, MC
TOLMAN, WB
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 356 - INOR
[37] USE OF AN OPTICALLY-ACTIVE GERMANIUM SPECIES FOR THE RESOLUTION OF DIASTEREOISOMERIC TRANSITION-METAL COMPLEXES WITH 5 DIFFERENT AND INDEPENDENT LIGANDS
CERVEAU, G
COLOMER, E
CORRIU, RJP
VIOUX, A
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 321 (03) : 327 - 334
[38] OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .50. P-LIGANDS AS OPTICALLY-ACTIVE RESOLVING AGENTS IN COMPLEXES C5H5M(CO)(NO)L,M=CR,MO,W
BRUNNER, H
DOPPELBERGER, J
CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (02): : 673 - 691
[39] OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .19. OPTICALLY-ACTIVE CYCLOPENTADIENYL DICARBONYLMOLYBDENUM DERIVATIVES OF SCHIFF-BASE OF PYRROLECARBALDEHYDE(2) WITH S-(-L-ALPHAMETHYLBENZYLAMINE
BRUNNER, H
HERRMANN, WA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 63 (DEC16) : 339 - 348
[40] OPTICALLY-ACTIVE QUATERNARY CARBON CENTERS FROM THE PHOTOADDITION OF CHROMIUM ALKOXYCARBENE COMPLEXES AND OPTICALLY-ACTIVE THIAZOLINES
THOMPSON, DK
SUZUKI, N
HEGEDUS, LS
SATOH, Y
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (05): : 1461 - 1467

← 1 2 3 4 5 →