CYANOSULFINES - AN UNEXPECTED REACTION OF N,N-BIS(TRIMETHYLSILYL)YNAMINES

被引:3
|
作者
SCHMID, T
HANACK, M
MAICHLE, C
STRAHLE, J
机构
[1] UNIV TUBINGEN,INST ORGAN CHEM,MORGENSTELLE 18,W-7400 TUBINGEN 1,GERMANY
[2] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN 1,GERMANY
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关键词
D O I
10.1002/anie.199302581
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cyanosulfines 2 and not the expected alkynylsulfinylamines 3, which might serve as precursors to alkenediazonium ions and alkynyl cations, arise in the reaction of bissilylated ynamines 1 with thionyl chloride. R = Ph, tBu, nPr, cyclohexyl.(~)[GRAPHICS]
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页码:258 / 259
页数:2
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