CYANOSULFINES - AN UNEXPECTED REACTION OF N,N-BIS(TRIMETHYLSILYL)YNAMINES

被引：3
|
作者：
SCHMID, T
HANACK, M
MAICHLE, C
STRAHLE, J
机构：
[1] UNIV TUBINGEN,INST ORGAN CHEM,MORGENSTELLE 18,W-7400 TUBINGEN 1,GERMANY
[2] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN 1,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期
关键词：
D O I：
10.1002/anie.199302581
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyanosulfines 2 and not the expected alkynylsulfinylamines 3, which might serve as precursors to alkenediazonium ions and alkynyl cations, arise in the reaction of bissilylated ynamines 1 with thionyl chloride. R = Ph, tBu, nPr, cyclohexyl.(~)[GRAPHICS]
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页码：258 / 259
页数：2
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