A novel kinetic mechanism of aqueous-phase ozone decomposition

被引：0

作者：

Virdis, A ^{[1
]}

Viola, A ^{[1
]}

Cao, G ^{[1
]}

机构：

[1] UNIV CAGLIARI,DIPARTIMENTO INGN CHIM & MAT,I-09123 CAGLIARI,ITALY

来源：

ANNALI DI CHIMICA | 1995年 / 85卷 / 11-12期

关键词：

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The mechanism of aqueous-phase ozone decomposition has been investigated. A relatively novel kinetic scheme which is able to predict the experimental behavior of ozone decompositon under a variety of operating conditions, has been obtained. By performing a sensitivity analysis of this complex mechanism, only 40% (44% for the case of pure water) of the involved reactions are required of accurately reproducing the chemistry of the corresponding kinetic scheme. The reduced mechanism obtained represents a single and a relatively simple kinetic scheme which predicts in a continuous fashion aqueous-phase ozone decomposition rates under a wide range of operating conditions.

引用

页码：633 / 647

页数：15

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