A novel kinetic mechanism of aqueous-phase ozone decomposition

被引：0
|
作者：
Virdis, A [1 ]
Viola, A [1 ]
Cao, G [1 ]
机构：
[1] UNIV CAGLIARI,DIPARTIMENTO INGN CHIM & MAT,I-09123 CAGLIARI,ITALY
来源：
ANNALI DI CHIMICA | 1995年 / 85卷 / 11-12期
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D O I：
暂无
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The mechanism of aqueous-phase ozone decomposition has been investigated. A relatively novel kinetic scheme which is able to predict the experimental behavior of ozone decompositon under a variety of operating conditions, has been obtained. By performing a sensitivity analysis of this complex mechanism, only 40% (44% for the case of pure water) of the involved reactions are required of accurately reproducing the chemistry of the corresponding kinetic scheme. The reduced mechanism obtained represents a single and a relatively simple kinetic scheme which predicts in a continuous fashion aqueous-phase ozone decomposition rates under a wide range of operating conditions.
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页码：633 / 647
页数：15
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