X-RAY STRUCTURE OF DICHLORO-[BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE] (DIMETHYL SULFOXIDE)RUTHENIUM(II)

被引：8
|
作者：
DELGADO, G [1 ]
RIVERA, AV [1 ]
SUAREZ, T [1 ]
FONTAL, B [1 ]
机构：
[1] UNIV LOS ANDES,FAC CIENCIAS,DEPT QUIM,MERIDA 5101,VENEZUELA
来源：
INORGANICA CHIMICA ACTA | 1995年 / 233卷 / 1-2期
关键词：
CRYSTAL STRUCTURES; RUTHENIUM COMPLEXES; TRIDENTATE PHOSPHINE COMPLEXES; CHELATING COMPLEXES;
D O I：
10.1016/0020-1693(94)04393-A
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex RuCl2(TRIPHOS)(DMSO). C6H5CH3 is monoclinic, P2(1)/c, with a=21.070(5), b=11.968(3), c=16.892(4) Angstrom, beta=107.7(2)degrees, V=4057.2 Angstrom(3), Z=4. The crystal structure consists of discrete molecules of the complex and solvent held together by normal van der Waals forces. The ruthenium atom is hexacoordinated. Dimethyl sulfoxide binds through the sulfur atom and the TRIPHOS ligand occupies three coordination sites.
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页码：145 / 149
页数：5
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