SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF CIS-DICHLORO(CYCLOPENTYLAMINE)(DIMETHYL SULPHOXIDE)PLATINUM(II)

被引：0
|
作者：
CALDWELL, G
NEUSE, EW
PERLWITZ, AG
FIELD, JS
RAMESAR, N
机构：
[1] UNIV WITWATERSRAND,DEPT CHEM,WITWATERSRAND 2050,SOUTH AFRICA
[2] UNIV NATAL,DEPT CHEM,PIETERMARITZBURG 3200,SOUTH AFRICA
来源：
TRANSITION METAL CHEMISTRY | 1995年 / 20卷 / 02期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
cis-Dichlorocyclopentylamine(dimethyl sulphoxide)platinum(II) is obtained, in addition to small quantities of the corresponding trans compound, by reaction of K2PtCl4 with cyclopentylamine in DMSO solution, where it is formed as the thermodynamically favoured isomer. An X-ray crystal structure analysis confirms the cis configuration. Coordination around the metal centre is square planar, and the ligand bond angles at the Pt atom are close to the expected values of 90 and 180 degrees. The DMSO ligand is S-coordinated to Pt. The Pt-Cl bond lengths, 2.299(2) and 2.317(2) Angstrom, are normal for structures of this type, as are the Pt-N and Pt-S bond distances, 2.059(5) and 2.191(2) Angstrom, respectively.
引用
收藏
页码：200 / 202
页数：3
相关论文
共 50 条
  • [1] Cis/trans influences in platinum(II) complexes. X-ray crystal structures of cis-dichloro(dimethyl sulfide)(dimethyl sulfoxide)platinum(II) and cis-dichloro(dimethyl sulfide)(dimethyl phenyl phosphine)platinum(II)
    Kapoor, P
    Lovqvist, K
    Oskarsson, A
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 1998, 470 (1-2) : 39 - 47
  • [2] CIS-DICHLORO(DIMETHYL "SULPHOXIDE)(2-PICOLINE)PLATINUM(II)
    MELANSON, R
    ROCHON, FD
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (NOV): : 3571 - 3573
  • [3] CIS-INFLUENCES AND TRANS-INFLUENCES IN PLATINUM(II) COMPLEXES - X-RAY CRYSTAL-STRUCTURE ANALYSIS OF CIS-DICHLORO(TRIETHYLPHOSPHINE)(TRIFLUOROPHOSPHINE)PLATINUM(II)
    HITCHCOCK, PB
    JACOBSON, B
    PIDCOCK, A
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (20): : 2043 - 2048
  • [4] STRUCTURE OF CIS-DICHLORO(DIMETHYL SULFOXIDE)(PYRIDINE)PLATINUM(II)
    BELSKY, VK
    KONOVALOV, VE
    KUKUSHKIN, VY
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 292 - 294
  • [5] CIS-DICHLORO(AMMINE)(DIMETHYL SULFOXIDE)PLATINUM(II)
    MELANSON, R
    ROCHON, FD
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAR): : 941 - 943
  • [6] Synthesis and structure of cis-dichloro(triphenylstibine)(dimethylsulfoxide)platinum(II)
    Sharutin, V. V.
    Senchurin, V. S.
    Pakusina, A. P.
    Fastovets, O. A.
    Ivanov, A. V.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (01) : 61 - 64
  • [7] Synthesis and structure of cis-dichloro(triphenylstibine)(dimethylsulfoxide)platinum(II)
    V. V. Sharutin
    V. S. Senchurin
    A. P. Pakusina
    O. A. Fastovets
    A. V. Ivanov
    [J]. Russian Journal of Inorganic Chemistry, 2010, 55 : 61 - 64
  • [8] CRYSTAL-STRUCTURE OF TRANS-DICHLORO(DIMETHYL "SULPHOXIDE)(2-PICOLINE)PLATINUM(II)
    MELANSON, R
    ROCHON, FD
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (APR): : 1125 - 1127
  • [9] Crystal structure of cis-dichloro (2,2′-dipyridylamine)-platinum(II)
    Li, DC
    Liu, DJ
    [J]. CRYSTAL RESEARCH AND TECHNOLOGY, 2004, 39 (04) : 359 - 362
  • [10] SYNTHESIS OF THE CIS-ISOMERS AND TRANSISOMERS OF TERT-BUTYLAMINEDICHLORO-(DIMETHYL SULPHOXIDE)PLATINUM(II) AND X-RAY STRUCTURE-ANALYSIS OF THE CIS COMPOUND
    NEUSE, EW
    PERLWITZ, AG
    FIELD, JS
    RAMESAR, N
    [J]. TRANSITION METAL CHEMISTRY, 1995, 20 (01) : 62 - 66
12345