Synthesis and structure of cis-dichloro(triphenylstibine)(dimethylsulfoxide)platinum(II)

被引:0
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作者
V. V. Sharutin
V. S. Senchurin
A. P. Pakusina
O. A. Fastovets
A. V. Ivanov
机构
[1] Blagoveshchensk State Pedagogical University,Institute of Geology and Nature Management, Far East Division
[2] Far East State Agricultural University,undefined
[3] Russian Academy of Sciences,undefined
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关键词
Central Atom; DMSO Molecule; PhCl; Tetrachloroplatinate; Bruker Nonius X8Apex;
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摘要
The platinum molecular complex cis-Cl2(Ph3Sb)(Me2S=O)Pt (I) was synthesized by the reaction of tetraphenylstibonium chloride with potassium tetrachloroplatinate in dimethyl sulfoxide. The crystal structure of square-planar complex I was determined by X-ray crystallography. The complex contains, in addition to chlorine atoms, triphenylstibine and DMSO molecules coordinated to the central atom. The bond lengths Pt-Cl, Pt-S, and Pt-Sb are 2.308(1), 2.350(1), 2.195(1), and 2.5118(4) Å, respectively. The compound is the first example of mixed-ligand platinum(II) complex in which the coordination sphere of the central atom contains, along with dimethyl sulfoxide ligand, a tertiary stibine ligand.
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页码:61 / 64
页数:3
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