SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (LIN(SIME(3))(2)MME(3))INFINITY (M=AL,GA) - AMIDO LIGANDS ISOELECTRONIC TO THE ALKYL GROUP -C(SIME(3))(3)

被引:29
|
作者
NIEMEYER, M [1 ]
POWER, PP [1 ]
机构
[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616
关键词
D O I
10.1021/om00012a013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structural characterization. of the lithium salts {LiN(SiMe(3))(2)MMe(3)}(infinity) (M = Al (1), Ga (2)) are described. The compounds are essentially isostructural and are associated into infinite chains that involve bridging by the lithium ion to an aluminum or gallium methyl group of a neighboring molecule.
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页码:5488 / 5489
页数:2
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