A NOVEL CIS-DIOXORUTHENIUM(VI) COMPLEX OF N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE (ME(3)TACN) FOR ORGANIC OXIDATION

被引：63
|
作者：
CHENG, WC [1 ]
YU, WY [1 ]
CHEUNG, KK [1 ]
CHE, CM [1 ]
机构：
[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期
关键词：
D O I：
10.1039/c39940001063
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The X-ray structure of [Ru(Me(3)tacn)O-2(CF3CO2)](+) shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) Angstrom and 118.3(4)degrees respectively, this Ru-VI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and Bu(t)OOH.
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收藏
页码：1063 / 1064
页数：2
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