A NOVEL CIS-DIOXORUTHENIUM(VI) COMPLEX OF N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE (ME(3)TACN) FOR ORGANIC OXIDATION

被引：63

作者：

CHENG, WC ^{[1
]}

YU, WY ^{[1
]}

CHEUNG, KK ^{[1
]}

CHE, CM ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期

关键词：

D O I：

10.1039/c39940001063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray structure of [Ru(Me(3)tacn)O-2(CF3CO2)](+) shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) Angstrom and 118.3(4)degrees respectively, this Ru-VI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and Bu(t)OOH.

引用

页码：1063 / 1064

页数：2

共 50 条

[11] 1, 4, 7-TRIAZACYCLONONANE AND N, N', N''-TRIMETHYL-1, 4, 7-TRIAZACYCLONONANE - 2 VERSATILE MACROCYCLES FOR THE SYNTHESIS OF MONOMERIC AND OLIGOMERIC METAL-COMPLEXES
WIEGHARDT, K
[J]. PURE AND APPLIED CHEMISTRY, 1988, 60 (04) : 509 - 516
[12] Synthesis of N,N',N''-tri(3,5-dinitro benzenesulfonyl)-1,4,7-triazacyclononane and N,N',N''-tri(3,5-diamino benzenesulfonyl)-1,4,7-triazacyclononane
Gao, JZ
Feng, YF
Kang, JW
[J]. SYNTHETIC COMMUNICATIONS, 1997, 27 (18) : 3219 - 3225
[13] COMPLEXES OF THALLIUM(I) AND THALLIUM(III) CONTAINING 1,4,7-TRIAZACYCLONONANE (L) LIGANDS - KINETICS AND MECHANISM OF THE REDUCTION OF [L2TLIII]3+ - CRYSTAL-STRUCTURE OF (N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)THALLIUM(I) HEXAFLUOROPHOSPHATE
WIEGHARDT, K
KLEINEBOYMANN, M
NUBER, B
WEISS, J
[J]. INORGANIC CHEMISTRY, 1986, 25 (09) : 1309 - 1313
[14] Reactions of (di)manganese carbonyl ions with 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3TACN) in the gas phase
van Beelen, ESE
Ingemann, S
[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2005, 19 (03) : 317 - 322
[15] 1,4,7-Triazacyclononane (tacn) with N,N′-bridging methylene-bis(phosphinic acid) group and its complexes
Pazderova, Lucia
Kubicek, Vojtech
Kotek, Jan
Hermann, Petr
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2021, 647 (12): : 1261 - 1268
[16] THE REACTIVITY OF THE (MN2(MU-O)(MU-CH3CO2)2)2+ CORE - THE CRYSTAL-STRUCTURES OF [1,4,7-TRIAZACYCLONONANE MN(N3)3] AND [N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE MN(S4)(H2O)]
WIEGHARDT, K
BOSSEK, U
NUBER, B
WEISS, J
[J]. INORGANICA CHIMICA ACTA, 1987, 126 (01) : 39 - 43
[17] Syntheses, characterizations and structures of ruthenium carbene and allenylidene complexes supported by 1,4,7-trimethyl-1,4,7-triazacyclononane (Me(3)tacn) ligands
Qian, Bing-Feng
Gao, Yang
Xu, Qian-Ya
Jia, Ai-Quan
Shi, Hua-Tian
Zhang, Qian-Feng
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2022, 976
[18] PREPARATION, CHARACTERIZATION, AND ELECTROCHEMISTRY OF NOVEL, AIR-STABLE NITROSYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN OF THE TYPE [M-NO)6,5,4 CONTAINING THE LIGAND N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE
BACKESDAHMANN, G
WIEGHARDT, K
[J]. INORGANIC CHEMISTRY, 1985, 24 (24) : 4044 - 4049
[19] ACID-BASE PROPERTIES OF THE CYCLIC TRIAMINE N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE AND CRYSTAL-STRUCTURE OF ITS MONOPROTONATED FORM [C9H22N3](CLO4)
WIEGHARDT, K
BRODKA, S
PETERS, K
PETERS, EM
SIMON, A
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1987, 42 (03): : 279 - 281
[20] Syntheses, characterizations and structures of ruthenium carbene and allenylidene complexes supported by 1,4,7-trimethyl-1,4,7-triazacyclononane (Me 3 tacn) ligands
Qian, Bing-Feng
Gao, Yang
Xu, Qian-Ya
Jia, Ai-Quan
Shi, Hua-Tian
Zhang, Qian-Feng
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2022, 976

← 1 2 3 4 5 →