A NOVEL CIS-DIOXORUTHENIUM(VI) COMPLEX OF N,N',N''-TRIMETHYL-1,4,7-TRIAZACYCLONONANE (ME(3)TACN) FOR ORGANIC OXIDATION

被引：63

作者：

CHENG, WC ^{[1
]}

YU, WY ^{[1
]}

CHEUNG, KK ^{[1
]}

CHE, CM ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期

关键词：

D O I：

10.1039/c39940001063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray structure of [Ru(Me(3)tacn)O-2(CF3CO2)](+) shows a cis-dioxoruthenium(VI) unit with the Ru=O distances and O-Ru-O angle being 1.717(9) and 1.715(9) Angstrom and 118.3(4)degrees respectively, this Ru-VI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and Bu(t)OOH.

引用

页码：1063 / 1064

页数：2

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