STRUCTURAL ASPECTS OF SUSPENSION POLY(VINYL CHLORIDE) - THE THERMAL ASPECTS OF RIGID SUSPENSION PVC

被引:10
|
作者
SCHERRENBERG, RL
REYNAERS, H
GONDARD, C
STEEMAN, PAM
机构
[1] LVM,B-3980 TESSENDERLO,BELGIUM
[2] DSM RES & PATENTS,6160 MD GELEEN,NETHERLANDS
[3] CATHOLIC UNIV LEUVEN,MACROMOLEC STRUCT CHEM LAB,CELESTIJNENLAAN 200F,B-3001 HEVERLEE,BELGIUM
关键词
POLY(VINYL CHLORIDE); THERMAL ANALYSIS; WAXS; DSC; SYNCHROTRON; GELATION; DIELECTRIC MEASUREMENTS;
D O I
10.1002/polb.1994.090320114
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The thermal aspects of a series of suspension PVC samples, polymerized at different temperatures, have been investigated using DSC, WAXS, and dielectric measurements. The observed thermal behavior, extending over a wide temperature range, is in line with the presence of ordered entities, having a wide distribution of size and perfection. The importance of small variations of the syndiotacticity on the crystallizability is demonstrated by cooling experiments. (C) 1994 John Wiley & Sons, Inc.
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页码:111 / 118
页数:8
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