MECHANISMS OF SOLVOLYTIC ALKENE-FORMING ELIMINATION-REACTIONS

被引：31
|
作者：
THIBBLIN, A
机构：
来源：
CHEMICAL SOCIETY REVIEWS | 1993年 / 22卷 / 06期
关键词：
D O I：
10.1039/cs9932200427
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Different types of alkene-forming elimination reactions that accompany substitution by the solvent as well as heterolysis reactions in non-nucleophilic solvents are treated. The article discusses kinetic deuterium isotope effects for such reactions and summarizes the use of extreme kinetic deuterium isotope effects as a mechanistic probe of reaction-branching in solvolytic reactions. Mechanistic borderlines are discussed.
引用
收藏
页码：427 / 433
页数：7
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