MECHANISMS OF SOLVOLYTIC ALKENE-FORMING ELIMINATION-REACTIONS

被引：31

作者：

THIBBLIN, A

机构：

来源：

CHEMICAL SOCIETY REVIEWS | 1993年 / 22卷 / 06期

关键词：

D O I：

10.1039/cs9932200427

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Different types of alkene-forming elimination reactions that accompany substitution by the solvent as well as heterolysis reactions in non-nucleophilic solvents are treated. The article discusses kinetic deuterium isotope effects for such reactions and summarizes the use of extreme kinetic deuterium isotope effects as a mechanistic probe of reaction-branching in solvolytic reactions. Mechanistic borderlines are discussed.

引用

页码：427 / 433

页数：7

共 50 条

[21] MECHANISMS OF ELIMINATION-REACTIONS .25. MODEL CALCULATIONS OF ISOTOPE EFFECTS IN ELIMINATION-REACTIONS - TEMPERATURE-DEPENDENCE, TUNNEL EFFECT, AND CONCERTED MODEL
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[J]. CHEMICA SCRIPTA, 1976, 10 (02): : 82 - 89
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