THE REACTIONS OF PHOSPHONODITHIOFORMATES WITH NUCLEOPHILIC-REAGENTS

被引：5
|
作者：
MASSON, S
机构：
[1] Laboratoire des Composés Thio-organiques, ISMRA - Université de Caen, Caen, 6 Boulevard du Maréchal Juin
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 95-6卷 / 1-4期
关键词：
PHOSPHONATE; DITHIOESTER; PHOSPHONODITHIOFORMATE; ADDITION OF NUCLEOPHILES;
D O I：
10.1080/10426509408034206
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of phosphonodithioformates with trialkylphosphites, organometallics, hydrides, radicals, amines and thiols have been studied. The results obtained demonstrate that these phosphonodithioesters can be used for carbon-carbon bond formation via their reaction with organometallics (ketene dithioacetals, homologation of aldehydes) and for the preparation of substituted methylene bis-(phosphonates) via stabilised ylids. They are radical trapping agents and also precursors of a large variety of new functionalised phosphonates which may have biological activities [thiocarbamoylphosphonates, (aminomethyl)-, [tris-(alkylthiomethyl)]- and (mercaptomethyl)-phosphonate derivatives].
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页码：127 / 144
页数：18
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