SYNTHESIS AND CHARACTERIZATION OF PALLADIUM COMPLEXES WITH BIS(BENZYLTHIO)METHANE

被引：6
|
作者：
FUCHITA, Y [1 ]
MARUYAMA, H [1 ]
KAWATANI, M [1 ]
HIRAKI, K [1 ]
机构：
[1] NAGASAKI UNIV,FAC ENGN,DEPT IND CHEM,NAGASAKI 852,JAPAN
来源：
POLYHEDRON | 1991年 / 10卷 / 06期
关键词：
D O I：
10.1016/S0277-5387(00)83612-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of Na2[PdCl4] with one equivalent and two equivalents of bis(benzylthio)methane (btm) yield trans-[PdCl2(mu-btm)]n (1) and trans-[PdCl2(btm-S)2] (2), respectively. Treatment of 2 with [PdCl2(NCMe)2] gives the face-to-face type palladium(II) complex, trans-[Pd2Cl4(mu-btm)2] (3), whereas the reaction of 2 with [Pd(dba)2] (dba = dibenzylideneacetone) produces the side-by-side type palladium(I) complex, [Pd2Cl2(mu-btm)2] (4). Treatment of 4 with dimethyl acetylenedicarboxylate gives the A-frame type complex [Pd2Cl2{mu-C2(CO2Me)2}(mu-btm)2].1/2CH2Cl2 (5). The complexes obtained in this study were characterized by elemental analysis, IR and NMR spectroscopy.
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页码：561 / 566
页数：6
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