Synthesis and characterization of palladium (II) complexes

被引：0
|
作者：
Mishra, A. K. [1 ]
Mishra, S. B. [2 ]
Manav, N. [1 ]
Kaushik, N. K. [1 ]
机构：
[1] Univ Delhi, Dept Chem, Delhi 110007, India
[2] Univ Free State, Dept Chem, ZA-9866 Bloemfontein, South Africa
来源：
REVIEWS IN INORGANIC CHEMISTRY | 2007年 / 27卷 / 06期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Palladium (II) complexes of type [Pd(L)Cl-2] [where, L= benzyl-N-thiohydrazide (L-1), (benzyl-N-thio)-1,3-propanediamine (L-2), benzaldehyde benzyl-N-thiohydrazone (L-3) and salicylaldehyde-benzyl-N-thiohydrazone (L-4)] have been synthesized. The thiohydrazides, thiodiamine and thiohydrazones can exist as thione-thiol tautomer and coordinate as as a bidentate N-S ligand. The ligands were found to act in monobasic bidentate fashion. The complexes have been characterized by elemental analysis, IR, mass, electronic and H-1 NMR spectroscopic studies.
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页码：449 / 458
页数：10
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