ELECTROINITIATED CATIONIC POLYMERIZATION OF EPSILON-CAPROLACTONE USING SACRIFICIAL ANODES

被引：0

作者：

PIERRE, G

LIMOSIN, D

DJELALI, NE

机构：

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS | 1991年 / 192卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polymerization of epsilon-caprolactone is carried out with metallic cationic initiators generated electrochemically. V, Ti, Cr, Al and Hg cations gave rise to polymers with molecular weights in the range 1000-13 000. Better yields and higher degrees of polymerization are obtained in the presence of [SbF6]- and [ClO4]- as anion of the supporting electrolyte, which is in accordance with the stability and the poor nucleophilicity of these anions.

引用

页码：2767 / 2775

页数：9

共 50 条

[31] LACTONE POLYMERS .3. POLYMERIZATION OF EPSILON-CAPROLACTONE
LUNDBERG, RD
KOLESKE, JV
WISCHMAN.KB
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (10PA): : 2915 - &
[32] Controlled polymerization of epsilon-caprolactone from macromolecules to microspheres
Slomkowski, S
MACROMOLECULAR SYMPOSIA, 1996, 103 : 213 - 228
[33] Ring opening polymerization of epsilon-caprolactone by bacterial protease
Zhang, LL
Deng, XM
Huang, ZT
BIOTECHNOLOGY LETTERS, 1996, 18 (09) : 1051 - 1054
[34] THE REACTIVITY-SELECTIVITY PRINCIPLE IN POLYMERIZATION - THE CASE OF POLYMERIZATION OF EPSILON-CAPROLACTONE
PENCZEK, S
DUDA, A
SLOMKOWSKI, S
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 54-5 : 31 - 40
[35] Aspects of the polymerization by microwave irradiation of epsilon-caprolactone, using sodium hydride as initiator
Contreras, Jesus Miguel
Sifontes, Jackson Javier
CIENCIA E INGENIERIA, 2013, 34 (02): : 73 - 80
[36] Nonthermal microwave effect on the ring opening polymerization of epsilon-caprolactone
Liu, Lijian
Cai, Shaojun
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
[37] RING-OPENING POLYMERIZATIONS - ON MECHANISM OF POLYMERIZATION OF EPSILON-CAPROLACTONE
YOUNG, RH
MATZNER, M
PILATO, LA
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1977, 173 (MAR20): : 33 - 33
[38] POLYMERIZATION MECHANISM OF EPSILON-CAPROLACTONE IN PRESENCE OF AROMATIC-AMINES
ESTRINA, GA
DAVTYAN, SP
ROZENBERG, BA
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1976, 18 (11): : 2438 - 2443
[39] POLYMERIZATION OF EPSILON-CAPROLACTONE INITIATED BY STABLE SALTS - INITIATION MECHANISM
MANOLOVA, NE
RASHKOV, IB
VELICHKOVA, RS
PANAYOTOV, IM
EUROPEAN POLYMER JOURNAL, 1984, 20 (05) : 463 - 465
[40] POLYMERIZATION OF EPSILON-CAPROLACTONE INITIATED BY ALUMINUM ISOPROPOXIDE TRIMER AND/OR TETRAMER
DUDA, A
PENCZEK, S
MACROMOLECULES, 1995, 28 (18) : 5981 - 5992

← 1 2 3 4 5 →