MOLECULAR ARCHITECTURE OF COPPER(I) THIOMETALLATE COMPLEXES - EXAMPLE OF A CUBANE WITH AN EXTRA FACE, (NPR4)3[MS4CU4CL5] (M = MO, W)

被引：115
|
作者：
JEANNIN, Y
SECHERESSE, F
BERNES, S
ROBERT, F
机构：
[1] Laboratoire de Chimie des Métaux de Transition, Université Pierre et Marie Curie, 75252 Paris Cédex 05
来源：
INORGANICA CHIMICA ACTA | 1992年 / 198卷
关键词：
D O I：
10.1016/S0020-1693(00)92393-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Thiometallates MS4(2-) (M = Mo, W) form with copper(I) heterobimetallic complexes which are interesting because of the versatility of the structural types obtained. The various structures obtained by addition of copper(I) to MS4(2-) are described and illustrated by examples recently reported in the literature. The synthesis and structural characterization of (NPr4)3[MS4Cu4Cl5] are given together with the connections which exist between 'open' and 'closed' cubane structures.
引用
收藏
页码：493 / 505
页数：13
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