Syntheses and crystal structures of heterometallic complexes [{Cu(en)2}2{Cu(en)2(NH3)}{M4Te4(CN)12}]·5H2O (M = Mo, W)

被引：0
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作者：
I. V. Kalinina
D. G. Samsonenko
V. A. Nadolinnyi
J. Lipkowski
V. P. Fedin
机构：
[1] Siberian Branch of the Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry
[2] Polish Academy of Sciences,Institute of Physical Chemistry
来源：
Russian Chemical Bulletin | 2004年 / 53卷
关键词：
clusters; molybdenum; tungsten; tellurium; copper; X-ray diffraction analysis; IR spectroscopy; ESR spectroscopy;
D O I：
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学科分类号：
摘要：
Evaporation of aqueous ammonia solutions of K7[Mo4Te4(CN)12]·12H2O or K6[W4Te4(CN)12]·5H2O, copper(ii) chloride, and ethylenediamine afforded the isostructural heterometallic complexes [{Cu(en)2}2{Cu(en)2(NH3)}{M4Te4(CN)12}]·5H2O (M = Mo or W), which were characterized by IR and ESR spectroscopy and X-ray diffraction analysis.
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页码：86 / 91
页数：5
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