Catalytic Activation of C-C and C-H Bonds in Alkanes under Mild Conditions

被引:0
|
作者
Akhmedov, V. M. [1 ]
机构
[1] Azerbaijan Natl Acad Sci, Inst Chem Problems, AZ-1143 Baku, Azerbaijan
关键词
alkane activation; metal nanoparticles; vapor metal condensation; catalysts;
D O I
10.1134/S2070050414040035
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Heterogeneous compositions capable of activating C-H and C-C bonds in alkanes under mild conditions have been obtained by reacting metal oxides with various morphologies with "metal solutions" prepared by metal vapor condensation. The physicochemical analysis carried out in this study suggests that the metal particles in these catalysts are mostly nanosized. The catalytic properties of the compositions have been investigated in the hydroreforming of C-5-C-16 n-alkanes. These compositions can be used to obtain promising catalysts for the structural conversion of n-alkanes into environmentally friendly high-octane gas-oline and lubricants.
引用
收藏
页码:253 / 259
页数:7
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