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Copper-catalyzed aerobic oxidative functionalization of C-H bonds of alkanes in the presence of acetaldehyde under mild conditions

被引：12
|
作者：
Hayashi, Yukiko [1 ]
Komiya, Naruyoshi [1 ]
Suzuki, Ken [2 ]
Murahashi, Shun-Ichi [1 ,3 ]
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan
[2] Asahi Kasei Chem Corp, R&D Planning & Business Dev, Chiyoda Ku, Tokyo 1010051, Japan
[3] Okayama Univ Sci, Fac Engn, Dept Chem, Kita Ku, Okayama 7000005, Japan
来源：
TETRAHEDRON LETTERS | 2013年 / 54卷 / 21期
关键词：
Copper catalyst; Aerobic oxidation; C-H functionalization; Hydrocarbon oxidation; TERT-BUTYL HYDROPEROXIDE; MOLECULAR-OXYGEN; PERACETIC-ACID; ALDEHYDES; COMPLEXES; EFFICIENT; MANGANESE; ALKENES; CYTOCHROME-P-450; MONOOXYGENASE;
D O I：
10.1016/j.tetlet.2013.03.074
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper-catalyzed oxidative functionalization of C-H bonds of alkanes with molecular oxygen has been performed in the presence of Cu(OAc)(2) catalyst and acetaldehyde in acetonitrile at 70 degrees C with extremely high turn-over numbers. (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2706 / 2709
页数：4
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