OBSERVATION OF ZR-91 NMR IN ZIRCONIUM-BASED METALS AND OXIDES

被引：25
|
作者：
BASTOW, TJ
SMITH, ME
STUART, SN
机构：
[1] CSIRO Division of Materials Science and Technology, Clayton, Vic. 3168
来源：
CHEMICAL PHYSICS LETTERS | 1992年 / 191卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(92)85380-S
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The characterisation by Zr-91 NMR at room temperature is reported for Zr metal (hexagonal close-packed), ZrH2 (tetragonal), ZrC (cubic), ZrCo (cubic), ZrO2 (monoclinic), ZrO2 (3 mol% Y2O3, tetragonal) and ZrO2 (9.3 mol% MgO). The density of states deduced from the Knight shift for zirconium metal agrees with band structure calculations. It is shown for the first time that the quadrupolar lineshape distinguishes between the various zirconia-based phases.
引用
收藏
页码：125 / 129
页数：5
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