ASYMMETRIC REDUCTION OF 2-AMINOBENZOPHENONE USING YEAST, RHODOSPORIDIUM-TORULOIDES

被引：0

作者：

KATO, M

SASAHARA, K

OCHI, K

AKITA, H

OISHI, T

机构：

[1] TOHO UNIV, SCH PHARMACEUT SCI, FUNABASHI, CHIBA 274, JAPAN

[2] INST PHYS & CHEM RES, SYNTHET ORGAN CHEM LAB, WAKO, SAITAMA 351, JAPAN

来源：

CHEMICAL & PHARMACEUTICAL BULLETIN | 1991年 / 39卷 / 10期

关键词：

2-AMINOBENZOPHENONE; 2-AMINOBENZHYDROL; ASYMMETRIC REDUCTION; MICROBIOLOGICAL REDUCTION; YEAST;

D O I：

暂无

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

(+/-)-N-Isonicotinoyl-2-amino-5-chlorobenzhydrol (1) is a rice plant growth regulator which shortens the second leaf sheaths. One of the enantiomers, (S)-1, was obtained by microbiological asymmetric reduction of 2-amino-5-chlorobenzophenone using Rhodosporidium toruloides followed by isonicotinoylation. Several substituted benzhydrol derivatives were also prepared by use of the same biological method and converted to N-isonicotinoyl compounds. The growth-regulating activities of these compounds were evaluated.

引用

页码：2498 / 2501

页数：4

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