HPLC DETERMINATION OF COPPER(II), COBALT(II) AND IRON(II) IN PHARMACEUTICAL PREPARATIONS USING 2-ACETYLPYRIDINE-4-PHENYL-3-THIOSEMICARBAZONE DERIVATIZING AGENT

被引：0

作者：

KHUHAWAR, MY

MEMON, ZP

LANJWANI, SN

机构：

来源：

CHROMATOGRAPHIA | 1995年 / 41卷 / 3-4期

关键词：

COLUMN LIQUID CHROMATOGRAPH; CU(II); CO(II); FE(II) IN PHARMACEUTICALS; PHENYL THIOSEMICARBAZONE DERIVATIVES;

D O I：

暂无

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Cu(II) Co(II) and Fe(II) in pharmaceutical preparations were determined using precolumn derivatization and solvent extraction with 2-acetylpyridine-4-phenyl-3-thiosemicarbazone (APPT) as complexing reagent. Liquid chromatography (LC) was carried out on a reversed phase C-18, column. The complexes were eluted isocratically with acetonitrile-water containing sodium acetate and tetrabutyl ammonium bromide as ion-pairing agents. The results obtained were compared with those using atomic absorption.

引用

页码：236 / 237

页数：2

共 50 条

[41] Simultaneous second derivative spectrophotometric determination of copper(II) and nickel(II) using 1-phenyl-1,2-propanedione-2-oxime thiosemicarbazone
Prasad, N. B. L.
Reddy, K. Hussain
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2007, 84 (05) : 474 - 477
[42] SYNTHESIS AND CHARACTERIZATION OF CHROMIUM(III), MANGANESE(II), IRON(III), COBALT(II), NICKEL(II), COPPER(II), CADMIUM(II) AND DIOXOURANIUM(VI) COMPLEXES OF 4(2-PYRIDYL)-1-(2,4-DIHYDROXYBENZALDEHYDE)-3-THIOSEMICARBAZONE
ABUELREASH, GM
KENAWY, IMM
ELAYAAN, U
KHATTAB, MA
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (10): : 914 - 918
[43] SYNTHESIS, CHARACTERIZATION AND FUNGITOXICITY OF MANGANESE(II), IRON(II), COBALT(II), NICKEL(II), COPPER(II) AND ZINC(II) COMPLEXES OF N-PHENYL-5-PHENYL-1,3,4-OXADIAZOLE-2-SULFONAMIDE AND 5-PHENYL-1,3,4-OXADIAZOLE-2-IMINO SULFONAMIDE
SINGH, H
SRIVASTAVA, VK
SHUKLA, SN
SRIVASTAVA, MK
UPADHYAY, MK
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (04): : 350 - 353
[44] SPECTROPHOTOMETRIC DETERMINATION OF IRON(II) AND COBALT(II) WITH 2,4-DIHYDROXY-3-NITROSOPYRIDINE
MUSUMECI, S
RIZZARELLI, E
FRAGALA, I
SAMMARTANO, S
BONOMO, RP
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1976, 282 (03): : 221 - 221
[45] EXTRACTION AND SPECTROPHOTOMETRIC DETERMINATION OF COBALT (II) WITH 3-PHENYL-2, 4-THIAZOLIDINEDIONE
Verdizade, A. N. A.
Kuliev, K. A.
Alieva, K. A.
Ismailova, R. A.
INDO AMERICAN JOURNAL OF PHARMACEUTICAL SCIENCES, 2018, 5 (11): : 12382 - 12391
[46] CHROMIUM(III), MANGANESE(II), IRON(III), COBALT(III), NICKEL(II) AND COPPER(II) COMPLEXES WITH 4-BENZOYLTHIOSEMICARBAZONE-3-METHYL-1-PHENYL-2-PYRAZOLIN-5-ONE
RANA, AK
SHAH, JR
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1982, 21 (09): : 929 - 931
[47] Potentiometric determination of the formation constants for complexes of 3,2′,2″-triaminopropyldiethylamine with cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II)
Hassan Keypour
Masoud Dehdari
Sadegh Salehzadeh
Kevin P. Wainwright
Transition Metal Chemistry, 2003, 28 : 425 - 429
[48] Potentiometric determination of the formation constants for complexes of 3,2′,2"-triaminopropyldiethylamine with cobalt(II), nickel(II), copper(II), zinc(II) and cadmium(II)
Keypour, H
Dehdari, M
Salehzadeh, S
Wainwright, KP
TRANSITION METAL CHEMISTRY, 2003, 28 (04) : 425 - 429
[49] Spectrophotometric determination of cobalt and iron in pharmaceutical preparation using 6-methyl-2-pyridinecarboxyaldehyde 4-phenyl-3-thiosemicarbazone as chromogenic reagent
Khuhawar, MY
Das Jaipal, P
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 1997, 19 (04): : 278 - 284
[50] 2-MERCAPTOPYRIMIDIN-4-OL (2-THIOURACIL) COMPLEXES OF COPPER(II), NICKEL(II), COBALT(II) AND IRON(III)
KHULLAR, IP
AGARWALA, U
AUSTRALIAN JOURNAL OF CHEMISTRY, 1974, 27 (09) : 1877 - 1883

← 1 2 3 4 5 →