PREPARATION AND CRYSTAL-STRUCTURE DETERMINATION OF [(C2H5)(4)N]2HG3CL8

被引：3

作者：

PABST, I ^{[1
]}

SONDERGELD, P ^{[1
]}

CZJZEK, M ^{[1
]}

FUESS, H ^{[1
]}

机构：

[1] FAC MED MARSEILLE,LCCMB MARSEILLE,CNRS,F-13326 MARSEILLE 15,FRANCE

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 01期

关键词：

X-RAY; TETRAETHYLAMMONIUM CHLOROMERCURATE; CLUSTER OF [HG3CL8](2-);

D O I：

10.1515/znb-1995-0113

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound has been prepared in two different ways: First, by boiling single crystals of [(C2H5)(4)N]HgCl3 in a mixture of n-hexane/n-octane [4:1] at T = 350 K, and second, in a synthesis from stoichiometric quantities of the components. X-ray structure analysis gave the stoichiometry [(C2H5)(4)N]2Hg3Cl8, monoclinic, space group P2(1), a = 7.538(3), b = 19.909(6), c = 10.274(3) Angstrom, beta = 95.13(1)degrees V = 1535.7(9) Angstrom(3), Z = 2. The basic [Hg3Cl8](2-)-units form broken zig-zag chains along [100]. The Hg-Cl distances within the [Hg3Cl8](2-) clusters range from 2.315(3) to 2.755(4) Angstrom. This is a new coordination type for halomercurates.

引用

页码：66 / 70

页数：5

共 50 条

[31] CUAL2CL8 - PREPARATION AND CRYSTAL-STRUCTURE
SCHAFER, H
BINNEWIES, M
LAUMANNS, R
WACHTER, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1980, 461 (02): : 31 - 34
[32] MERCURIC HALIDE ADDUCTS - SYNTHESIS AND STRUCTURE OF [CO(NH3)5CL]HG3CL8 AND [CO(NH3)5HPO4]2HG3CL8
TERZIS, A
MENTZAFOS, D
TAZMIRRIAHI, HA
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 101 (02): : 77 - 83
[33] TRIETHYLALUMINUM-BASED FERROCENYLALANES - SYNTHESIS AND CRYSTAL-STRUCTURE OF (ETA-5-C5H5)FE[ETA-5-C5H4AL2(C2H5)4CL]
ROBINSON, GH
BOTT, SG
ATWOOD, JL
JOURNAL OF COORDINATION CHEMISTRY, 1987, 16 (03) : 219 - 224
[34] CRYSTAL-STRUCTURE OF ETHYLTRIPHENYLPHOSPHONIUM DIBROMOCUPRATE(I), [P(C2H5)(C6H5)3][CUBR2]
ANDERSSON, S
JAGNER, S
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1985, 39 (07): : 515 - 518
[35] SYNTHESIS AND CRYSTAL-STRUCTURE OF GRIGNARD COMPOUNDS C5H5MGCL.O(C2H5)2 AND C5ME5MGCL.O(C2H5)2
DOHMEIER, C
LOOS, D
ROBL, C
SCHNOCKEL, H
FENSKE, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 448 (1-2) : 5 - 8
[36] CRYSTAL-STRUCTURE OF NICKEL BIS-N,N-DIETHYLPHENYLAZO-THIOFORMAMIDE, NI[(C6H5)NNCSN(C2H5)2]2
HAZELL, RG
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1976, 30 (05): : 322 - 326
[37] CRYSTAL-STRUCTURE OF N-CHLOROACETYLCHLOROTHIAZIDE, C9CL2H7N3O5S2
MAGNUSSO.B
LINDQVIS.O
ACTA CHEMICA SCANDINAVICA, 1972, 26 (04): : 1411 - &
[38] CRYSTAL-STRUCTURE OF BIS(TETRAETHYLAMMONIUM) HEXAFLUOROTUNGSTATE(IV) DIHYDRATE, ((C2H5)(4)N)(2)(WF6)(H2O)(2)
REIBENSPIES, JH
KLAUSMEYER, KK
DARENSBOURG, DJ
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1995, 210 (11): : 882 - 882
[39] CRYSTAL-STRUCTURE DETERMINATION OF SOLVATE HGBR2.C4H8O
FREY, M
LILIGNY, H
LEDESERT, M
BULLETIN DE LA SOCIETE FRANCAISE MINERALOGIE ET DE CRISTALLOGRAPHIE, 1971, 94 (5-6): : 467 - &
[40] CRYSTAL-STRUCTURE OF [(C2H5)4N]4CU4CL12, A NEW STRUCTURAL TYPE FOR A TETRANUCLEAR COPPER(II) HALIDE COMPLEX
WILLETT, RD
GEISER, U
INORGANIC CHEMISTRY, 1986, 25 (25) : 4558 - 4561

← 1 2 3 4 5 →