PREPARATION AND CRYSTAL-STRUCTURE DETERMINATION OF [(C2H5)(4)N]2HG3CL8

被引：3

作者：

PABST, I ^{[1
]}

SONDERGELD, P ^{[1
]}

CZJZEK, M ^{[1
]}

FUESS, H ^{[1
]}

机构：

[1] FAC MED MARSEILLE,LCCMB MARSEILLE,CNRS,F-13326 MARSEILLE 15,FRANCE

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 01期

关键词：

X-RAY; TETRAETHYLAMMONIUM CHLOROMERCURATE; CLUSTER OF [HG3CL8](2-);

D O I：

10.1515/znb-1995-0113

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound has been prepared in two different ways: First, by boiling single crystals of [(C2H5)(4)N]HgCl3 in a mixture of n-hexane/n-octane [4:1] at T = 350 K, and second, in a synthesis from stoichiometric quantities of the components. X-ray structure analysis gave the stoichiometry [(C2H5)(4)N]2Hg3Cl8, monoclinic, space group P2(1), a = 7.538(3), b = 19.909(6), c = 10.274(3) Angstrom, beta = 95.13(1)degrees V = 1535.7(9) Angstrom(3), Z = 2. The basic [Hg3Cl8](2-)-units form broken zig-zag chains along [100]. The Hg-Cl distances within the [Hg3Cl8](2-) clusters range from 2.315(3) to 2.755(4) Angstrom. This is a new coordination type for halomercurates.

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页码：66 / 70

页数：5

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