Preparation and properties of 3-(N,N-Dimethylamino)propyl thallium compounds

被引：5
|
作者：
Thiele, KH
Herbrich, T
机构：
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 12期
关键词：
organothallium chelate complexes; dimethylamino-propyl ligands; MOVPE;
D O I：
10.1002/zaac.19956211208
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
TlCl3 reacts with Me(2)NCH(2)CH(2)CH(2)Li in molar ratio 1:2 with formation of (Me(2)NCH(2)CH(2)CH(2))(2)TlCl (1) which can be transfered with MeLi into (Me(2)NCH(2)CH(2)CH(2))(2)TlMe (2) and with excess of Me(2)NCH(2)CH(2)CH(2)Li into (Me(2)NCH(2)CH(2)CH(2))(3)Tl (3) respectively. Comproportionation of 1 with TlCl3 yields rather instable Me(2)NCH(2)CH(2)CH(2)TlCl(2) (4) from which Me(2)NCH(2)CH(2)CH(2)TlMe(2) (5) can be obtained by alkylation with MeLi. 1-3 and 5 were characterized by elemental analysis, mass spectra, H-1- and C-13-n.m.r spectra.
引用
收藏
页码：2025 / 2028
页数：4
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