Preparation of diarylamines by the addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes

被引：9
|
作者：
Yang, TL [1 ]
Cho, BP [1 ]
机构：
[1] Univ Rhode Isl, Coll Pharm, Dept Biomed Sci, Kingston, RI 02881 USA
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 40期
关键词：
aryllithium; diarylamine; nitroarene;
D O I：
10.1016/j.tetlet.2003.07.002
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes in THF (-78degreesC) affords the corresponding diarylamines in one-pot and the reaction appears to be general in scope. A 'nitroso'-based mechanism is proposed for this novel nitroreductive N-arylation reaction. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7549 / 7552
页数：4
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