THERMAL-DEGRADATION PRODUCTS OF A N,N-DIALKYLAMIDE - IDENTIFICATION BY GC/EI-MS, GC/CI-MS AND GC/FTIR

被引:0
|
作者
DAGNAC, T
GUILLOT, JM
ROULPH, C
LECLOIREC, P
CHARBONNEL, MC
机构
[1] ECOLE MINES ALES,GENIE ENVIRONM IND LAB,F-30319 ALES,FRANCE
[2] CEA,CE VALRHO MARCOULE,DRDD,SEMP,GEA,F-30205 BAGNOLS SUR CEZE,FRANCE
关键词
THERMAL DEGRADATION; N; N-DIALKYLAMIDE; MASS SPECTROMETRY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; EXTRACTANT;
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Due to their utilization in the nuclear process, the N,N-dialkylamides' thermal stability must be well known. The degradation of such a compound has been studied in a temperature range of 175 to 255 degrees C under different atmospheres. The degradation mixture was separated by gas chromatography (GC) and the structural characterization of the 15 major products was ensured by the combined application of Fourier transform infrared spectroscopy (FTIR) and mass spectrometry (MS).
引用
收藏
页码:120 / 124
页数:5
相关论文
共 50 条
  • [31] IDENTIFICATION AND CHARACTERIZATION OF E, Z ISOMERS FOR ACID DEGRADENTS OF SECONDARY ALCOHOL IN API BY HS/GC/EI-MS
    Yarbagi, Kaviraj
    Rajana, Nagaraju
    Babu, J. Moses
    Rao, B. Venkateswara
    Douglas, Paul
    INTERNATIONAL JOURNAL OF PHARMACEUTICAL SCIENCES AND RESEARCH, 2016, 7 (11): : 4637 - 4643
  • [32] GC-MS (EI) OF DRUGS AND BIOTRANSFORMATION PRODUCTS IN TOXICOLOGICAL ANALYSIS
    MUELLER, RK
    HERZSCHUH, R
    ZSCHOCKE, D
    JOURNAL OF THE FORENSIC SCIENCE SOCIETY, 1981, 21 (02): : 127 - 127
  • [33] A detailed identification study on high-temperature degradation products of oleic and linoleic acid methyl esters by GC-MS and GC-FTIR
    Berdeaux, Olivier
    Fontagne, Stephanie
    Semon, Etienne
    Velasco, Joaquin
    Sebedio, Jean Louis
    Dobarganes, Carmen
    CHEMISTRY AND PHYSICS OF LIPIDS, 2012, 165 (03) : 338 - 347
  • [34] ANALYSIS OF N-NITROSAMINES BY CID GC MS/MS
    ANDRZEJEWSKI, D
    HAVERY, DC
    SPHON, JA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 : 62 - ANYL
  • [35] Thermal degradation of α-pinene using a Py–GC/MS
    Bruno Coudour
    Khaled Chetehouna
    Laurent Lemée
    Pierre Bertin
    Jean-Pierre Garo
    Journal of Thermal Analysis and Calorimetry, 2019, 137 : 1315 - 1328
  • [36] GC-MS and GC-FTIR characterization of products - From classical freshman and sophomore syntheses
    Amenta, DS
    DeVore, TC
    Gallaher, TN
    Zook, CM
    Mosbo, JA
    JOURNAL OF CHEMICAL EDUCATION, 1996, 73 (06) : 572 - 575
  • [37] GC-MS and GC-FTIR characterization of products: From classical freshman and sophomore syntheses
    James Madison University, Harrisonburg, VA 22807, United States
    不详
    J Chem Educ, 6 (572-575):
  • [38] THE THERMAL-DEGRADATION OF POLY(ARYL ETHER ETHER KETONE) (PEEK) AS MONITORED BY PYROLYSIS GC/MS AND TG/MS
    DAY, M
    COONEY, JD
    WILES, DM
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1990, 18 (02) : 163 - 173
  • [39] Diazinon decomposition by soil bacteria and identification of degradation products by GC-MS
    Thabit, Tamer Mohamed Ahmed Mohamed
    El-Naggar, Medhat Ahmed Hassan
    SOIL & ENVIRONMENT, 2013, 32 (02) : 96 - 102
  • [40] Analysis of chlorothalonil and degradation products in soil and water by GC/MS and LC/MS
    Chaves, Alicia
    Shea, Damian
    Danehower, David
    CHEMOSPHERE, 2008, 71 (04) : 629 - 638