THERMAL-DEGRADATION PRODUCTS OF A N,N-DIALKYLAMIDE - IDENTIFICATION BY GC/EI-MS, GC/CI-MS AND GC/FTIR

被引：0
|
作者：
DAGNAC, T
GUILLOT, JM
ROULPH, C
LECLOIREC, P
CHARBONNEL, MC
机构：
[1] ECOLE MINES ALES,GENIE ENVIRONM IND LAB,F-30319 ALES,FRANCE
[2] CEA,CE VALRHO MARCOULE,DRDD,SEMP,GEA,F-30205 BAGNOLS SUR CEZE,FRANCE
来源：
ANALUSIS | 1995年 / 23卷 / 03期
关键词：
THERMAL DEGRADATION; N; N-DIALKYLAMIDE; MASS SPECTROMETRY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; EXTRACTANT;
D O I：
暂无
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Due to their utilization in the nuclear process, the N,N-dialkylamides' thermal stability must be well known. The degradation of such a compound has been studied in a temperature range of 175 to 255 degrees C under different atmospheres. The degradation mixture was separated by gas chromatography (GC) and the structural characterization of the 15 major products was ensured by the combined application of Fourier transform infrared spectroscopy (FTIR) and mass spectrometry (MS).
引用
收藏
页码：120 / 124
页数：5
相关论文
共 50 条
  • [21] CHARACTERIZATION OF CITRUS AND KIWI FLAVORS AND THEIR DEGRADATION PROCESSES BY COMBINATION OF GC FTIR AND GC MS
    FISCHBOCK, G
    PFANNHAUSER, W
    KELLNER, R
    MIKROCHIMICA ACTA, 1988, 1 (1-6) : 27 - 30
  • [22] Analysis of the degrading products of carbofuran by Sphingomonas sp. with GC/MS and GC/FTIR
    College of Life Science, Nanjing Agricultural University, Key Lab of Microbiological Engineering Agricultural Environment, Ministry of Agriculture, Nanjing 210095, China
    不详
    Guang Pu Xue Yu Guang Pu Fen Xi, 2006, 9 (1716-1719):
  • [23] Integration of GC/EI-MS and GC/NCI-MS for simultaneous quantitative determination of opiates, amphetamines, MDMA, ketamine, and metabolites in human hair
    Wu, Ya-Hsueh
    Lin, Keh-liang
    Chen, Su-Chin
    Chang, Yan-Zin
    JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2008, 870 (02): : 192 - 202
  • [24] Thermal degradation of various lignins by TG-MS/FTIR and Py-GC-MS
    Brebu, Mihai
    Tamminen, Tarja
    Spiridon, Iuliana
    JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 104 : 531 - 539
  • [25] Analysis of drugs of abuse in hair by automated solid-phase extraction, GC/EI/MS and GC ion trap/CI/MS
    Girod, C
    Staub, C
    FORENSIC SCIENCE INTERNATIONAL, 2000, 107 (1-3) : 261 - 271
  • [26] Characterization and Identification of Petroleum Hydrocarbons and Biomarkers by GC-FTIR and GC-MS
    Sharma, K.
    Sharma, S. P.
    Lahiri, S. C.
    PETROLEUM SCIENCE AND TECHNOLOGY, 2009, 27 (11) : 1209 - 1226
  • [27] THERMAL-DEGRADATION OF LIQUID POLYSULFIDE POLYMERS - PYROLYSIS GC MS AND THERMOGRAVIMETRIC STUDIES
    RAO, MR
    RADHAKRISHNAN, TS
    JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (02) : 855 - 873
  • [28] N,N-Dimethyltryptamine and dichloromethane:: Rearrangement of quaternary ammonium salt product during GC-EI and CI-MS-MS analysis
    Brandt, Simon D.
    Martins, Claudia P. B.
    Freeman, Sally
    Dempster, Nicola
    Wainwright, Mark
    Riby, Philip G.
    Alder, John F.
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2008, 47 (01) : 207 - 212
  • [29] Consensus Structure Elucidation Combining GC/EI-MS, Structure Generation, and Calculated Properties
    Schymanski, Emma L.
    Gallampois, Christine M. J.
    Krauss, Martin
    Meringer, Markus
    Neumann, Steffen
    Schulze, Tobias
    Wolf, Sebastian
    Brack, Werner
    ANALYTICAL CHEMISTRY, 2012, 84 (07) : 3287 - 3295
  • [30] Identification and Determination of Nicorandil and its Degradation Products by HPLC and GC/MS
    Zhong Zhou CHENG1
    Chinese Chemical Letters, 2006, (08) : 1057 - 1060
12345