GAS-PHASE INORGANIC-CHEMISTRY - LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOFORMAMIDATES

被引：7
|
作者：
BOPEGEDERA, AMRP [1 ]
FERNANDO, WTML [1 ]
BERNATH, PF [1 ]
机构：
[1] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 09期
关键词：
D O I：
10.1021/j100372a035
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction products of calcium and strontium metal vapors with formamide were studied by using laser spectroscopic techniques. Three electronic transitions were observed for the resulting metal monoformamidates, MNHCOH. The formamidate ligand is probably bonding to the metal in a bidentate manner. The metal-ligand stretching vibrational frequencies were assigned from the low-resolution spectra. © 1990 American Chemical Society.
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页码：3547 / 3549
页数：3
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