GAS-PHASE INORGANIC-CHEMISTRY - LASER SPECTROSCOPY OF CALCIUM AND STRONTIUM MONOCARBOXYLATES

被引：6

作者：

OBRIEN, LC ^{[1
]}

BRAZIER, CR ^{[1
]}

KINSEYNIELSEN, S ^{[1
]}

BERNATH, PF ^{[1
]}

机构：

[1] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 09期

关键词：

D O I：

10.1021/j100372a034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The calcium and strontium monocarboxylate free radicals were made by the gas-phase reaction of the metal vapors with carboxylic acids. Three electronic transitions, Ã-X̃, B̃-X̃, and C̃-X̃, were detected by laser-induced fluorescence. Metal-ligand stretching frequencies were derived from these low-resolution spectra. The carboxylate ligand binds in a bidentate manner to the metal. © 1990 American Chemical Society.

引用

页码：3543 / 3547

页数：5

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