CONFORMATIONAL DEPENDENCE OF THE VICINAL H-1, H-1 COUPLING-CONSTANT IN 1,2-3,4-DIEPOXIDES

被引：0

作者：

NIKLES, M ^{[1
]}

SEQUIN, U ^{[1
]}

机构：

[1] UNIV BASEL,INST ORGAN CHEM,ST JOHANNS RING 19,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON | 1992年 / 48卷 / 04期

关键词：

1,2-3,4-DIEPOXIDES; CONFORMATION; KARPLUS RELATIONSHIP; H-1; H-1 COUPLING CONSTANTS;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A survey of all 1,2:3,4-diepoxides, of which X-ray structure analyses and H-1-NMR data have been published, shows that in conformationally rigid systems a Karplus-like relationship exists between the torsional angle around the inter-epoxide bond and the corresponding vicinal proton-proton coupling constant.

引用

页码：683 / 686

页数：4

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