CONFORMATIONAL DEPENDENCE OF THE VICINAL H-1, H-1 COUPLING-CONSTANT IN 1,2-3,4-DIEPOXIDES

被引：0
|
作者：
NIKLES, M [1 ]
SEQUIN, U [1 ]
机构：
[1] UNIV BASEL,INST ORGAN CHEM,ST JOHANNS RING 19,CH-4056 BASEL,SWITZERLAND
来源：
TETRAHEDRON | 1992年 / 48卷 / 04期
关键词：
1,2-3,4-DIEPOXIDES; CONFORMATION; KARPLUS RELATIONSHIP; H-1; H-1 COUPLING CONSTANTS;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A survey of all 1,2:3,4-diepoxides, of which X-ray structure analyses and H-1-NMR data have been published, shows that in conformationally rigid systems a Karplus-like relationship exists between the torsional angle around the inter-epoxide bond and the corresponding vicinal proton-proton coupling constant.
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页码：683 / 686
页数：4
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