ENANTIOSELECTIVE CATALYTIC REDUCTION OF ACETOPHENONE WITH BORANE IN THE PRESENCE OF CYCLIC ALPHA-AMINO-ACIDS AND THEIR CORRESPONDING BETA-AMINO ALCOHOLS

被引：27

作者：

MEHLER, T ^{[1
]}

BEHNEN, W ^{[1
]}

WILKEN, J ^{[1
]}

MARTENS, J ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,D-26129 OLDENBURG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(00)86168-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The direct application of alpha-amino acids as chiral auxiliaries in the enantioselective catalytic reduction of acetophenone with borane in refluxing toluene has been investigated. A comparison with the corresponding beta-amino alcohols as optically active catalysts is involved.

引用

页码：185 / 188

页数：4

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