ENANTIOSELECTIVE CATALYTIC REDUCTION OF ACETOPHENONE WITH BORANE IN THE PRESENCE OF CYCLIC ALPHA-AMINO-ACIDS AND THEIR CORRESPONDING BETA-AMINO ALCOHOLS

被引：27
|
作者：
MEHLER, T [1 ]
BEHNEN, W [1 ]
WILKEN, J [1 ]
MARTENS, J [1 ]
机构：
[1] UNIV OLDENBURG,FACHBEREICH CHEM,D-26129 OLDENBURG,GERMANY
来源：
TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 02期
关键词：
D O I：
10.1016/S0957-4166(00)86168-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The direct application of alpha-amino acids as chiral auxiliaries in the enantioselective catalytic reduction of acetophenone with borane in refluxing toluene has been investigated. A comparison with the corresponding beta-amino alcohols as optically active catalysts is involved.
引用
收藏
页码：185 / 188
页数：4
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