COMPLEX RESONANCES IN THE PREDISSOCIATION OF CS2

被引：54
|
作者：
KIM, B
YOSHIHARA, K
LEE, S
机构：
[1] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN
[2] KYUNGHEE UNIV,DEPT CHEM,KYONGGI DO 449701,SOUTH KOREA
来源：
PHYSICAL REVIEW LETTERS | 1994年 / 73卷 / 03期
关键词：
D O I：
10.1103/PhysRevLett.73.424
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
We present detailed quantum mechanical analysis of the complex resonances observed in molecular predissociation. The complex features in the photodissociation spectrum of Cs2 are reproduced well by the close-coupling calculation including three channels. A very narrow resonance with a linewidth of approximately 2 x 10(-7) cm-1 is predicted. It is shown that q reversal can occur in predissociation with only two channels involved.
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页码：424 / 427
页数：4
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