COMPLEX RESONANCES IN THE PREDISSOCIATION OF CS2

被引：54
|
作者：
KIM, B
YOSHIHARA, K
LEE, S
机构：
[1] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN
[2] KYUNGHEE UNIV,DEPT CHEM,KYONGGI DO 449701,SOUTH KOREA
来源：
PHYSICAL REVIEW LETTERS | 1994年 / 73卷 / 03期
关键词：
D O I：
10.1103/PhysRevLett.73.424
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
We present detailed quantum mechanical analysis of the complex resonances observed in molecular predissociation. The complex features in the photodissociation spectrum of Cs2 are reproduced well by the close-coupling calculation including three channels. A very narrow resonance with a linewidth of approximately 2 x 10(-7) cm-1 is predicted. It is shown that q reversal can occur in predissociation with only two channels involved.
引用
下载
收藏
页码：424 / 427
页数：4
相关论文
共 50 条
  • [11] K-dependent predissociation dynamics of CS2 in the 210-216 nm region
    Chen, Jun
    Guo, Ying
    Zhou, Xiaoguo
    Shi, Yong
    Liu, Shilin
    Ma, Xingxiao
    JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (25): : 5382 - 5387
  • [12] [(TRIPHOS)CO(CS2)CR(CO)5] - DINUCLEAR HETEROMETAL COMPLEX CONTAINING A CS2 BRIDGING GROUP
    BIANCHINI, C
    MELI, A
    ORLANDINI, A
    SACCONI, L
    INORGANICA CHIMICA ACTA, 1979, 35 (02) : L375 - L376
  • [13] Detailed study of the predissociation dynamics of the 1B2(1Σu+) state of CS2
    Mank, A.
    Starrs, C.
    Jego, M.N.
    Hepburn, J.W.
    Journal of Chemical Physics, 1996, 104 (10):
  • [14] A detailed study of the predissociation dynamics of the B-1(2)((1)Sigma(+)(u)) state of CS2
    Mank, A
    Starrs, C
    Jego, MN
    Hepburn, JW
    JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (10): : 3609 - 3619
  • [15] Resonances in the predissociation of the A 2ΠΩ state of MgBr
    J Chem Phys, 10 (4091):
  • [16] CS2 for an IS Curriculum
    Cornell, Lee D.
    ITICSE 2007: 12TH ANNUAL CONFERENCE ON INNOVATION & TECHNOLOGY IN COMPUTER SCIENCE EDUCATION, 2007, : 340 - 340
  • [17] THE CS2 DICATION
    MAZUMDAR, S
    MARATHE, VR
    KUMAR, SVK
    MATHUR, D
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1988, 86 : 351 - 355
  • [18] Giant resonances in cold electron scattering by CS2 -: art. no. 093201
    Jones, NC
    Field, D
    Ziesel, JP
    Field, TA
    PHYSICAL REVIEW LETTERS, 2002, 89 (09)
  • [19] Measurement of the absorption cross sections of unstable CS based on the dynamic equilibrium of CS2 and CS in the photolysis of CS2
    Zhang, Yungang
    Wang, Yongda
    Liu, Yunjie
    Ai, Xinyu
    Zhang, Zhiguo
    Li, Jimeng
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2020, 243
  • [20] CORRELATION OF ABAR, A-32 STATE OF CS2 WITH STATES OF LINEAR CS2
    BARROW, T
    DIXON, RN
    MOLECULAR PHYSICS, 1973, 25 (01) : 137 - 144
12345